In this regard, low-temperature bioreduction has been developed [8–11]. For example, Li and his coworkers  reported a green synthesis of Ag-Pd alloyed nanoparticles using the aqueous extract of the Cacumen platycladi leaves as reducing agent and stabilizing
agent . They found that the biomolecules like saccharides, polyphenols, or carbonyl compounds perform as the reducing agent and (NH)C = O groups are responsible for the GSK872 stabilization of selleckchem the AgPd alloyed nanoparticles. Recently, reduction using electron beam has been exploited . The reduction by electron beam can be directly performed with electricity only. No chemicals are needed except the precursors of metal ions. It is a green reduction for only reduction process itself is considered. The disadvantage of the electron beam reduction is that the specific equipment and high vacuum operation are required. On the other hand, some cold plasmas like glow discharge, radio frequency (RF) discharge, and microplasma contain a large amount of electrons. These energetic electrons can be employed as the reducing agent. Mougenot et al.  reported a formation of surface PdAu alloyed nanoparticles on carbon
using argon RF plasma reduction. Mariotti and Sankaran  and Yan et al.  reported a microplasma reduction for synthesis of alloyed nanoparticles at atmospheric pressure. These represented CB-839 datasheet a remarkable progress in the green and energy-efficient synthesis of alloyed nanoparticles. Herein, we report a simple and facile method for the preparation of AuPd alloyed nanoparticles on the anodic
aluminum oxide (AAO) surface using room-temperature electron reduction with argon glow discharge as electron source. This reduction operates in a dry way. It requires neither chemical reducing Tolmetin agent nor capping agent. The influence of chemicals on the formed nanoparticles can be eliminated. Glow discharge is well known as a conventional cold plasma phenomenon with energetic electrons. It has been extensively applied for light devices like neon lights and fluorescent lamps. It has also been employed for the preparation of nanoparticles and catalysts [16–20]. Methods Synthesis of AuPd alloyed nanoparticles AAO with 0.02-μm hole (0.1 mm in thickness, 13 mm in diameter; Whatman International Ltd., Germany) was used as substrate. A solution of HAuCl4 and PdCl2 was used as metal precursors. A drop of the solution (approximately 30 μL) was dropped on the AAO surface and spread out spontaneously. Then, the AAO sample was put on a glass slide. Once the liquid volatilized, the slide was placed into the glow discharge tube. The pressure of the discharge tube was set at approximately 100 Pa. The argon glow discharge was then initiated by applying high voltage (approximately 1,000 V) using a high-voltage generator (TREK 20/20B, TREK, Inc., Lockport, NY, USA) to the gas.